CobaltMaghrebV1, Maroc, Analysis, bibRecord, 000027

Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)

Identifieur interne : 000027 ( Maroc/Analysis ); précédent : 000026; suivant : 000028

Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)

Auteurs : Abderrazzak Assani [Maroc] ; Mohamed Saadi [Maroc] ; Mohammed Zriouil [Maroc] ; Lahcen El Ammari [Maroc]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.

RBID : PMC:3414095

Abstract

The title compound, Pb₂Mn₃(HPO₄)₂(PO₄)₂, was synthesized by a hydrothermal method. All atoms are in general positions except for one Mn atom which is located on an inversion center. The framework of the structure is built up from PO₄ tetrahedra and two types of MnO₆ octahedra, one almost ideal and the other very distorted with one very long Mn—O bond [2.610 (4) Å compared an average of 2.161 Å for the other bonds]. The centrosymetric octahedron is linked to two distorted MnO₆ octahedra by an edge common, forming infinite zigzag Mn₃O₁₄ chains running along the b axis. Adjacent chains are linked by PO₄ and PO₃(OH) tetrahedra through vertices or by edge sharing, forming sheets perpendicular to [100]. The Pb²⁺ cations are sandwiched between the layers and ensure the cohesion of the crystal structure. O—H⋯O hydrogen bonding between the layers is also observed.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414095

DOI: 10.1107/S1600536812033259
PubMed: 22904702
PubMed Central: 3414095

Affiliations:

Maroc

Links to Exploration step

PMC:3414095

Le document en format XML

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<front><div type="abstract" xml:lang="en"><p>The title compound, Pb<sub>2</sub>
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Serveur d'exploration sur le cobalt au Maghreb

Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)

Dilead(II) trimanganese(II) bis(hydrogenphosphate) bis(phosphate)

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

	Serveur d'exploration sur le cobalt au Maghreb
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